Richmond, VA
Former capital of the Confederacy
The Omni hotel is the place to stay. Centrally located to the financial district. If you have some extra time between meetings, head down Cary Street for a cobblestone neighborhood with cute shops. Also, drive down to the James River for the Richmond National Battlefield Park. Some incredible Civil War artifacts and displays.
In terms of travel around the city, 195 south of Richmond has a number of tolls along the way. I've gotten along fine having never gone on this stretch, so don't worry about taking alternate routes.

